| Calibration dataset with fivefold validation | Calibration dataset | Validation dataset | Entire dataset | ||
---|---|---|---|---|---|---|
Model 1 (without DAS) | Without feature reduction | R2 | 0.84 | 0.86 | 0.90 | 0.87 |
 |  | RMSE | 60.70 | 57.53 | 51.34 | 55.39 |
 |  | RPD | 2.49 | 2.62 | 3.16 | 2.77 |
Model 2 (with DAS) | Without feature reduction | R2 | 0.87 | 0.88 | 0.92 | 0.89 |
RMSE | 54.68 | 51.89 | 45.54 | 49.89 | ||
RPD | 2.76 | 2.90 | 3.57 | 3.08 | ||
With feature ‘Hue’ reduction | R2 | 0.87 | 0.88 | 0.92 | 0.90 | |
RMSE | 54.60 | 51.61 | 45.37 | 49.64 | ||
RPD | 2.76 | 2.92 | 3.58 | 3.09 |