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Table 4 Chemical assignment of Raman characteristic wavenumbers

From: Quantitative visualization of photosynthetic pigments in tea leaves based on Raman spectroscopy and calibration model transfer

Wavenumbers/cm−1

Assignment

References

788/800/1046/1073/1114/1222/1553

Chlorophyll a

[51]

971

β-carotene [τ(C11-C12)]

[52]

988

Chlorophyll

[53]

1026

β-carotene [ρ(9Me), ν(C8 − C9)]

[52]

1068/1155/1165/1265/1392/1530/1555

Chlorophyll a

[54]

1128/1160/1210/1380/1465/1523/1567/1644

Chlorophyll b

[54]

1133

β-carotene

[55]

1137

β-carotene [ν(C10 − C11)]

[52]

1144

Chlorophyll [ν(CN), δ(CNC)]

[53]

1145

Chlorophyll a [ν(CaN), δ(CaNCa)]

[52]

1149

β-carotene [14 − 15, 15H, 15 = 15 ‘]

[55]

1157

β-carotene [ν(C14 − C15), δ(C15 − H)]

[52]

1172

β-carotene [5 − 4, 18r, 6 − 7]

[55]

1186

Chlorophyll a [ν(CmC10), δ (CbH)]

[52]

1187

β-carotene [10H, 11H, 8 − 9]

[55]

1191

β-carotene [δ(C10 − H), δ(C11 − H)]

[52]

1216

β-carotene [ν(C12 − C13), δ(C14 − H)]

[52]

1225

Chlorophyll [δ(CH), δ(CH2)]

[53]

1226

β-carotene [12 − 13, 14H, 15 = 15 ‘]

[54]

1281

β-carotene [15H, 14H, CCC15b]

[55]

1310

β-carotene [12H, 11 = 12, 15 = 15 ‘]

[55]

1322

β-carotene [δ(C12 − H), ν(C11-C12)]

[52]

1347

β-carotene [12H, 11 = 12, 15 = 15 ‘]

[55]

1450

β-carotene [δas(9Me), δas(13Me)]

[52]

1485

β-carotene [13 = 14, 11 = 12, 12H]

[55]

1518

Lutein [C=C stretching vibration]

[56]

1524

Chlorophyll a [ν(CbCb), ν(CaCb)]

[52]

1528

Carotenoids [ν1(C=C)]

[52]

1542

Chlorophyll a [ν(CbCb)]

[52]

1552

Chlorophyll a [ν(CaCb), ν(CbCb)]

[52]

1562

β-carotene [11 = 12, 15H, 12H]

[55]