Table 1 List of standards used for matrix free and matrix adapted calibration.
| Â | Â | Â | Â | Calibration2 | Calibration3 | ||
|---|---|---|---|---|---|---|---|
Number | Substance | [M+H] + | Retention time [min] | Linearity (r) § | LOD [pg/μL] | Linearity (r) § | LOD [pg/μL] |
1 | 13C6-jasmonic acid-isoleucine (13C6-JA-Ile) | 421 | 6.86 | 1.00 | 20.60 | 0.99 | 116 |
2 | Jasmonic acid-isoleucine (JA-Ile) | 415 | 6.86 | 1.00 | 20.80 | 0.99 | 117 |
3 | 2H4-salicylic acid (2H4-SA) | 234 | 8.77 | 0.98 | 24.40 | 0.98 | 167 |
4 | Salicylic acid (SA) | 230 | 8.77 | 0.97 | 24.80 | 0.98 | 165 |
5 | 2H6-abscisic acid (2H6-ABA) | 362 | 9.01 | 0.98 | 19.40 | 0.98 | 163 |
6 | Abscisic acid (ABA) | 356 | 9.02 | 0.99 | 18.70 | 0.98 | 165 |
7 | Indole-3-carboxylic acid (ICA) | 253 | 9.08 | 0.93 | 41.30 | 0.91 | 355 |
8 | Royal jelly acid (Tr IS) | 278 | 9.26 | 0.99 | 12.00 | 0.98 | 181 |
9 | Cinnamic acid (CA) | 240 | 9.34 | 0.99 | 23.90 | 0.97 | 203 |
10 | Jasmonic acid (JA) | 302 | 9.43 | 0.98 | 19.60 | 0.98 | 155 |
11 | Traumatol | 306 | 9.85 | 0.99 | 12.90 | 0.98 | 174 |
12 | Indole-3-acetic acid (IAA) | 267 | 9.94 | 0.98 | 19.30 | 0.99 | 297 |
13 | Traumatin | 304 | 9.96 | 1.00 | 5.30 | 0.98 | 168 |
14 | 9,10-2H2-dihydro-jasmonic acid (D2-JA) | 306 | 10.13 | 1.00 | 11.30 | 0.98 | 180 |
15 | Traumatic acid | 320 | 10.15 | 0.99 | 11.20 | 0.96 | 250 |
16 | Hexadecatrieonic acid (16:3) | 342 | 10.29 | 0.99 | 17.00 | 0.99 | 132 |
17 | (9 S, 13 S)-12-oxo-phytodienoic acid (OPDA) | 384 | 10.89 | 1.00 | 10.30 | 0.98 | 147 |
18 | Hexadecadienoic acid (16:2) | 344 | 10.93 | 0.99 | 14.90 | 0.98 | 147 |
19 | Gibberellin A3 (GA3) | 438 | 11.27 | 0.93 | 42.30 | 0.96 | 246 |
20 | 2H2-OPC 8:0 | 388 | 11.59 | 0.94 | *1 | 0.96 | *1 |
21 | Linolenic acid (18:3) | 370 | 12.83 | 1.00 | 7.80 | 1.00 | 70 |
22 | Hexadecenoic acid (16:1) | 346 | 13.20 | 0.99 | 19.00 | 0.99 | 95 |
23 | Heptadecenoic acid (17:1) | 360 | 13.78 | 1.00 | 4.10 | 0.97 | 195 |
24 | Linoleic acid (18:2) | 372 | 14.22 | 0.97 | 8.60 | 0.96 | 123 |
25 | Hexadecanoic acid (16:0) | 348 | 14.53 | 1.00 | 5.20 | 0.99 | 114 |
26 | Octadecenoic acid (18:1) | 374 | 14.86 | 0.99 | 14.70 | 0.99 | 94 |
27 | Heptadecanoic acid (17:0) | 362 | 16.09 | 1.00 | 7.50 | 0.99 | 119 |
28 | Stearic acid (18:0) | 376 | 17.59 | 1.00 | 7.90 | 0.99 | 117 |